Education Texas Tech University, Texas, U.S.A. Dissertation Title: Dynamics of probes in ionic liquids from ultrafast to ultraslow

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1 Dr. Fehmi Bardak Department of Physics, Faculty of Art and Sciences, Manisa Celal Bayar University, Manisa, Turkey. Phone: Web : fehmibardak.cbu.edu.tr Education Ph.D. (Chemical Physics, Chemistry) Texas Tech University, Texas, U.S.A. Dissertation Title: Dynamics of probes in ionic liquids from ultrafast to ultraslow Ph.D. (Atomic and Molecular Physics, Physics) (Partial fulfillment) Gazi University, Institute of Science and Technology, Ankara, Turkey M.S. (Atomic and Molecular Physics, Physics) Celal Bayar University, Institute of Science and Technology, Manisa, Turkey Thesis Title: Synthesis and spectroscopic investigations on some metal halide complexes of biologically important ligands B.S. (Physics) Celal Bayar University Faculty of Art and Sciences, Manisa, Turkey

2 Experiences Instructor General Physics Department of Physics, Celal Bayar University Officer Ombudsman Ministry of National Education of Turkey Teaching Assistant Physical Chemistry Laboratory (Chemistry ) Department of Chemistry and Biochemistry, Texas Tech University Research Assistant Projects: Probe Rotational and Translational Diffusion in Ionic Liquids Near the Glass Transition Studied by Fluorescence Recovery After Photobleaching Probing Nanostructural Organization in the Intermolecular and Rotational Dynamics of Small Molecules in Ionic Liquids Using Optical Kerr Effect Spectroscopy Department of Chemistry and Biochemistry, Texas Tech University Assistant Atomic and Molecular Physics Laboratory, Geometrical and Optical Physics Laboratory Projects: Two projects on the theoretical and experimental investigation of vibrational spectroscopy of some metal halide complexes of pyridine based ligands Department of Physics, Celal Bayar University

3 Publications PH.D. Dissertation (in Chemical Physics) (Mentor: Prof. Dr. Edward L. Quitevis) Bardak, F., Dynamics of probes in ionic liquids from ultrafast to ultraslow, Texas Tech University, (Awarded with Song Price Award for Outstanding Dissertation, the best Ph.D. degree dissertation in the department) M.S. Thesis (in Atomic and Molecular Physics) (Mentor: Prof. Dr. Ahmet Ataç) Bardak, F., Bazı izonikotinik asit N-oksit metal halojen bileşiklerinin sentezlenmesi ve yapılarının IR spektroskopisi ile tayini, Celal Bayar Üniversitesi, A. Books/ Book chapters: E. L. Quitevis, F. Bardak, D. Xiao, L. G. Hines, Jr., P. Son, R. A. Bartsch, P. Yang, and G. A. Voth "OKE spectroscopy and molecular dynamics simulations of polar and nonpolar molecules in ionic liquids", in Ionic Liquids: Science and Applications, A. E. Visser, N. J. Bridges, R. D. Rogers, Eds.; ACS Symposium Series 1117; American Chemical Society, Washington, DC, 2012; Chapter 13, pp

4 B. Peer-reviewed journal articles (SCI): 1. S. Gatfaoui, N. Issaoui, A. Mezni, F. Bardak, T. Roisnel, A. Atac, and H. Marouani, Synthesis, structural and spectroscopic features, and investigation of bioactive nature of a novel organic-inorganic hybrid material 1 H - 1,2,4-triazole-4-ium trioxonitrate, J. Mol. Struct., vol. 1150, pp , N. Issaoui, H. Ghalla, S. A. Brandán, F. Bardak, H. T. Flakus, A. Atac, and B. Oujia, Experimental FTIR and FT-Raman and theoretical studies on the molecular structures of monomer and dimer of 3-thiopheneacrylic acid, J. Mol. Struct., vol. 1135, pp , L. Xue, F. Bardak, G. Tamas, and E. L. Quitevis, Comparative study of the intermolecular dynamics of imidazolium-based ionic liquids with linear and branched alkyl chains: OHD-RIKES measurements, Phys. Chem. Chem. Phys., vol. 19, no. 6, N. Issaoui, H. Ghalla, F. Bardak, M. Karabacak, N. Aouled Dlala, H. T. Flakus, and B. Oujia, Combined experimental and theoretical studies on the molecular structures, spectroscopy, and inhibitor activity of 3-(2- thienyl)acrylic acid through AIM, NBO,FT-IR, FT-Raman, UV and HOMO-LUMO analyses, and molecular docking, J. Mol. Struct., vol. 1130, pp , Etem Kose, Mehmet Karabacak, Fehmi Bardak, Ahmet Atac Spectral investigations of 2,5-difluoroaniline by using mass, electronic absorption, NMR, and vibrational spectra Journal of Molecular Structure 1123 (2016) Bardak, F., Karaca, C., Bilgili, S., Atac, A., Mavis, T., Asiri, A. Karabacak, M., Kose, E. "Conformational, electronic, and spectroscopic characterization of isophthalic acid (monomer and dimer structures) experimentally and by DFT." Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 165 (2016) Fehmi Bardak, Justin R. Rajian, Pillhun Son, Edward L. Quitevis Heterogeneous dynamics in ionic liquids at the glass transition: Fluorescence recovery after photo bleaching measurements of probe rotational motion fromtg 6Kto Tg+4K, Journal of Non-Crystalline Solids 407 (2015) (Invited paper for IDMRCS7 special issue.) 8. E. Kose, F. Bardak, A. Atac, M. Karabacak, M.A. Cipiloglu, Determination of structural and vibrational spectroscopic features of neutral and anion forms of dinicotinic acid by using NMR, infrared and Raman experimental methods combined with DFT and HF Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 114 (2013) 38 45

5 9. F. Bardak, D. Xio, L.G. Hines Jr., P. Son, R.A.Bartsch, E.L. Quitevis, P. Yang, and G.A. Voth. Nanostructural organization in acetonitrile/ionic liquid mixtures: Molecular dynamics simulations and optical Kerr effect spectroscopy, ChemPhysChem, 13 (2012) (Featured on the cover of ionic liquids special issue.) 10. F. Bardak, A. Ataç, M. Kurt, Infrared and raman study of some isonicotinic acid metal (II) halide and tetracyanonickelate complexes, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71 (2009) A. Ataç,and F. Bardak, Synthesis and vibrational spectroscopic study of some metal (ii) halide and tetracyanonickelate complexes of isonicotinic acid, Turk. J. Chemistry, 30 (2006) N. Can, A. Ataç, F. Bardak, S.E.Sözerli Can, Spectroscopic and luminescence properties of an isonicotinic acid N-oxide Zn(II) complex, Turk. J. Chemistry, 29 (2005) N. Can, S.E.Sözerli Can, A. Atac, F. Bardak, Structural characterization and luminescence properties of an isonicotinic acid N-oxide Mn(II) complex, Polyhedron, 23 (2004)

6 C. Oral presentations and posters at international conferences 1. Mustafa Ali Cipiloglu, Fehmi Bardak, Ahmet Atac, Mehmet Karabacak, Effect of Halogenation on the Bioactivity and Spectroscopic Features in Transition Metal Complexes of Pharmaceutical Ligands: The Case of Co 2 (INO) 3 X 4 Complexes. XIIIth International Conference on Molecular Spectroscopy, The European Academy of Sciences, (Oral presentation) 2. Edward L Quitevis, Fehmi Bardak, Rakhitha Udugama Arachchilage, Kayla D Mendoza, Matthew E Heberle, Anthony R Toops, George Tamas, Dynamic heterogeneity in ionic liquids near the glass transition: Fluorescence recovery after photobleaching measurements of probe rotational and translational diffusion in ionic liquids Physical Chemistry of Ionic Liquids Symposium, 248 th ACS National Meeting, San Francisco, August 10-14, 2014.(Invited Presenter) 3. Kayla Mendoza, Rakhitha Udugamaarachchilage, Fehmi Bardak, George Tamas, Edward Quitevis, Measurement of Ultraslow Rotational Dynamics of Probes in Imidazolium-Based Ionic Liquids Near and Below the Glass Transition Temperature: Studying the Role of Structural Heterogeneity on Dynamic Heterogeneity, Bulletin of the American Physical Society, APS March Meeting 2014, Volume 59, Number 1(Oral presentation) 4. L. Xue, F. Bardak, G. Tamas, E.Gurung, E. L. Quitevis, Y. Koh, and S. L. Simon, Comparative Study of the Intermolecular Dynamics and Physical Properties of Branched and Linear Alkyl Chain Imidazolium Ionic Liquids, Focus Session: Solvation, Dynamics, and Reactivity in Complex Environments II, American Physical Society March Meeting 2014, Denver, Co., March 5, (Oral presentation) 5. E. L.Quitevis, F. Bardak, R. Udugama Arachchilage, K. Mendoza, G. Tamas Dynamic Heterogeneity in Ionic Liquids near the Glass Transition: Fluorescence Recovery After Photobleaching Measurements of Probe Rotational Diffusion, 7th International Discussion Meeting on Relaxation in Complex Systems, Barcelona, Spain, July 24, (Oral presentation) 6. Edward L. Quitevis, Fehmi Bardak, Lianjie Xue, George Tamas, Probing the Role of Cation and Anion Structure in the Intermolecular Dynamics of Ionic Liquids through OKE Spectroscopy, 5 th International Congress on Ionic Liquids (COIL-5), April 21-25, 2013, Vilamoura, Algarve, Portugal. (Poster) 7. Lianjie Xue, Fehmi Bardak, Edward L. Quitevis, Effect of branch structure on the intermolecular dynamics of ionic liquids, Inaugural Texas Soft Matter Meeting, January 11, 2013; University of Houston, Houston, TX, USA. (Oral presentation)

7 8. Fehmi Bardak, Justin R. Rajian, George Tamas, Edward L. Quitevis, Dynamic heterogeneity and rotational diffusion in ionic liquids near and below Tg, Inaugural Texas Soft Matter Meeting, January 11, 2013; University of Houston, Houston, TX, USA. (Oral presentation) 9. Fehmi Bardak, Steven T. Patton, Pillhun Son, Richard A. Bartsch, Edward L. Quitevis, Rotational diffusion of probe molecules in ionic liquids near the glass transition: Fluorescence recovery after photobleaching measurements, Dynamics and Jamming in Complex Environments, 244 th ACS National Meeting & Exposition, August 19-23, 2012, Philadelphia, Pennsylvania, USA. (Oral presentation) 10. Edward L. Quitevis, Fehmi Bardak,, Dong Xiao, Larry G. Hines Jr, Pillhun Son, Richard A. Bartsch, Peng Yang, Gregory A. Voth, Optical Kerr effect spectroscopy and molecular dynamics simulations of nonpolar and polar molecules in ionic liquids, 243 rd ACS National Meeting & Exposition, March ; San Diego, California, USA. (Oral presentation) 11. Fehmi Bardak, Justin R. Rajian, Larry G. Hines, Richard A. Bartsch, Edward L. Quitevis, Dynamic Heterogeneity in Ionic Liquids near and below the Glass Transition: Rotational Diffusion of Probes in 1-Butyl- 3-methylimidazolium Hexafluorophosphate, Joint Fall 2012 Meeting of the Texas Sections of the APS, AAPT, and Zone 13 of the SPS, Volume 57, Number 10, October 25 27, 2012; Lubbock, Texas, USA. (Oral presentation) 12. Fehmi Bardak, Ahmet ATAC, Larry G. Hines Jr.,Richard A.Bartsch, and Edward L. Quitevis, An Optical Kerr Effect Study of Ultrafast Dynamics and Intermolecular Interactions in Ionic Liquid/Hexafluorobenzene Mixtures, 11th Annual Graduate Student Research Poster Competition, March 26-30, 2012; Texas Tech University, Lubbock, TX, USA. (Poster) 13. Fehmi Bardak, Justin R. Rajian, Larry G. Hines Jr., Richard A. Bartsch, and E. L. Quitevis, Rotational motion of probe molecules in [Bmim] + [PF 6 ] - near glass transition, 4th Congress on Ionic Liquids (COIL-4), June 14-18, 2011; Crystal City, Washington, VA, USA. (Poster) 14. Z. Çalişir, M. Kurt, A. Ataç, F. Bardak Experimental and Theoretical FT-IR Spectroscopic Analysis of 2,4 Pyridinedicarboxylic Acid and Vibrational Properties Turkish Physical Society 27th International Physics Congress, September 14-17, 2010; İstanbul, Turkey. (Oral presentation) 15. A. Ataç, E. Çulcular, F. Bardak, The investigation of geometrical properties of 2,5 pyridine dicarboxylic acid; Synthesis and vibrational properties of its some metal halogen compounds 6 th Nano Science and Nano Technology Conference, June 15-18, 2010; Izmir, TURKEY. (Poster)

8 16. A. Ataç, Z. Çalişir, F. Bardak, Experimental and theoretical FT-IR spectroscopic analysis of 3,5 pyridinedicarboxylic acid; Synthesis and vibrational properties of its some metal halogen compounds 6 th Nano Science and Nano Technology Conference, June 15-18, 2010, Izmir, TURKEY, (Poster) 17. A. Ataç, F. Bardak, Z. Çalışır, Synthesis and Spectroscopic Studies on Some Metal(II) Iodide Complexes of 3,5 Pyridine-di-carboxylic acid ; in Balkan Physics Letters Special Issue, Turkish Physical Society 24 th International Physics Congress, August 28-31, 2007; Malatya, Turkey. (Poster) 18. A. Ataç and F. Bardak, Synthesis and Fourier transform infrared spectroscopic study on some metal (II) halide complexes isonicotinic acid N-oxide, XXVIII European Congress on Molecular Spectroscopy Conference, September 3-8, 2006, Istanbul, TURKEY. (Poster) 19. A. Ataç, F. Bardak, and K. Büke, Synthesis and Spectroscopic Investigation of Cadmium and Copper Chloride Complexes of Nicotinamide N- Oxide, Turkish Physical Society 23rd International Physics Congress, September 13-16, 2005; Muğla, TURKEY. (Poster) 20. A. Ataç And F. Bardak, Synthesis and Spectroscopic Studies on Cadmium Halide Complexes of Isonicotinic Acid,Turkish Physical Society 22nd International Physics Congress, September 14, 2004; Bodrum/Muğla, TURKEY. (Poster)

9 E. Papers in nationwide journals: 1. Bardak, F. "Investigation of Electronic Structure - Bioactive Nature Relation in Niacin Derivates by DFT Calculations and Molecular Docking". Celal Bayar Üniversitesi Fen Bilimleri Dergisi 13 (2017): A. Ataç, E. Çulcular, F. Bardak, M. A. Çipiloğlu, The Inverstigation of Geometrical Properties of 2,5 Pyridinedicarboxylic Acid, Synthesis and Vibrational Properties of Its Some Metal Halogen Compounds, C.B.Ü. Fen Bilimleri Dergisi, ISSN

10 F. Oral presentations and posters in nationwide conferences 1. Etem Köse, Ahmet Ataç, Fehmi Bardak, Çağlar Karaca 2,3-dimethylanisole molekülüne ait yapısal, titreşim, elektronik ve kimyasal kaymaların spektroskopik incelemesi Adım Fizik Günleri VI, Temmuz 2017, Balıkesir / Türkiye (Oral presentation) 2. Etem Kose, Ahmet Atac, Fehmi Bardak, Çağlar Karaca 2,4-dimethylanisole molekülünün, titreşim, kimyasal kayma durumları ve elektronik özelliklerinin spektroskopik olarak incelenmesi Adım Fizik Günleri VI, Temmuz 2017, Balıkesir / Türkiye (Oral presentation) 3. Çağlar Karaca, Ahmet Ataç, Fehmi Bardak, Etem Köse Xanthone un TD-CAM-B3LYP ve State Specific PCM hesaplamaları Adım Fizik Günleri VI, Temmuz 2017, Balıkesir / Türkiye (Oral presentation) 4. Fehmi Bardak, Ahmet Ataç, Mehmet Karabacak, Selda Sadi, C n C 1 imntf 2 (n=1,2,..8 ) iyonik sıvılarında elektronik yapı, spektroskopik özellikler ve iyonlar arası zayıf etkileşmelerin alkali kuyruk uzunluğuna bağlılığının teorik olarak incelenmesi, Adım Fizik Günleri V, Nisan 2016, Eskişehir, Türkiye (Oral presentation) 5. Fehmi Bardak, Mehmet Karabacak, Ahmet Ataç, Fatma Aydoğar, Halojenli geçiş metali komplekslerinde metalin ve halojenin elektronik yapı ve biyoaktiviteye etkisinin incelenmesi, Adım Fizik Günleri V, Nisan 2016, Eskişehir, Türkiye (Oral presentation) 6. Selda Sadi, Fehmi Bardak, Ahmet Ataç, 1-butyl-3-methylimidazolium bis ( trifluoro methyl sulfonyl ) imide iyonik sıvısının elektronik yapı, spektroskopik özellikler ve iyonlar arası zayıf etkileşmelerinin teorik olarak incelenmesi, Adım Fizik Günleri IV, Mayis 2015, Kütahya, Türkiye (Oral presentation) 7. Fatma Aydoğar, Fehmi Bardak, Ahmet Ataç, Geçiş metali komplekslerinin elektronik yapısı, spektroskopik özellikleri ve biyoaktiflerinin incelenmesi: Cu(INO) 2 Cl 2 nin durumu, Adım Fizik Günleri IV, Mayis 2015, Kütahya, Türkiye (Oral presentation) 8. Fehmi Bardak, Tuğba Maviş, Ahmet Ataç, Mehmet Karabacak, Theoretical Investigation of The Effect of Chain Length on The Molecular Vibrations and Electronic Structure of Ionic Liquids: The Case of 1,3-Dialkyl Methylimidazolium Trifluoromethanesulfonates, Adım Fizik Günleri III, Nisan 2014, Süleyman Demirel Üniversitesi, Isparta, Türkiye (Poster) 9. Fehmi Bardak, Sibel Bilgili, Ahmet Ataç, Mehmet Karabacak, Theoretical Investigation of The Effect of Chain Length on The Molecular Vibrations and Electronic Structure of Ionic Liquids: The Case of 1-Alkyl-3- Methylimidazolium Trifluoromethanesulfonates, Adım Fizik Günleri III, Nisan 2014, Süleyman Demirel Üniversitesi, Isparta, Türkiye (Poster)

11 10. A. Ataç ve F. Bardak, Synthesis and investigation of spectroscopic properties of some isonicotinic acid N- Oxide, cadmium and nickel halogen compounds, Geleneksel Fizik Gunleri, Erzurum (Poster)

12 G. Projects 1. Project Title: Bazı bioaktif ligandların kristal yapılı geçiş metali bileşiklerinin sentezi ve yapılarının deneysel ve teorik yöntemlerle tayini Project code : , Celal Bayar Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi Principle Investigator: Prof.Dr. Ahmet ATAÇ, Department of Physics, Faculty of Art and Sciences, Celal Bayar University. Task in Project : Researcher 2. Project Title: Probing Nanostructural Organization in the Intermolecular and Orientational Dynamics of Small Molecules in Ionic Liquids Using Optical Kerr Effect Spectroscopy Dates: Project code : CHE , National Science Foundation, USA Principle Investigator : Prof.Dr. Edward Quitevis, Department of Chemistry&Biochemistry, Texas Tech University, Lubbock, TX, USA Task in Project : Researcher-FRAP measurements 3. Project Title: Probing Nanostructural Organization in Room Temperature Ionic Liquids Using Optical Kerr Effect Spectroscopy Dates: Project code : CHE , National Science Foundation, USA Principle Investigator : Prof.Dr. Edward Quitevis, Department of Chemistry&Biochemistry, Texas Tech University, Lubbock, TX, USA Task in Project : Researcher-OKE measurements 4. Project Title: Piridinedikarboksilik Asitlerin Yarı Deneysel, Hartree-Fock ve Yoğunluk Fonksiyonu Teorisi (DFT) Yöntemleri ile Geometrik ve Titreşimsel Özelliklerinin İncelenmesi ve Bazı Metal Halojen Komplekslerinin sentezlenerek titreşimsel spektroskopi ile incelenmesi, Project code : FEF , Celal Bayar Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi Principle Investigator : Prof.Dr. Ahmet ATAÇ, Department of Physics, Faculty of Art and Sciences, Celal Bayar University.

13 Task in Project : Researcher 5. Project Title: Bazı İzonikotinik asit Metal Halojenür Komplekslerinin Yapılarının Titreşimsel Spektroskopi ile İncelenmesi Project code : FEF , Celal Bayar Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimi Principle Investigator : Prof.Dr. Ahmet ATAÇ, Department of Physics, Faculty of Art and Sciences, Celal Bayar University. Task in Project : Researcher