LEAP Atıksu Kimyası Yeterlik Testleri Programı Nisan 2012 Mart 2013

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1 distribution EFF 31 EFF 32 EFF 33 EFF 34 EFF 35 EFF 36 date 10/04/ /06/ /07/ /10/ /12/ /01/2013 Group 1 Group 2 Group 3 Group 4 Group 5 Group 6 Group 7 Group 8 Group 9 Group 10 Group 11 Group 12 Group 13 Group 14 Group 15 Group 16 Group 17 Group 18 Group 19 Group 20 Group 21 Group 22 Group 23 Group 24 Group 25 Group 26 Group 27 Group 28 R0121 R0122 R0123 R0124 R0221 R0222 R0223 R0224 R0321 R0322 R0323 R0324 R0421 R0422 R0423 R0424 R0521 R0522 R0523 R0524 R0621 R0622 R0623 R0624 R0721 R0722 R0723 R0724 R0821 R0822 R0823 R0824 R0911 R0912 R1011 R1012 R1111 R1112 R1211 R1212 R1311 R1312 R1411 R1412 R1511 R1512 R1611 R1612 R1711 R1712 R1811 R1812 R1911 R1912 R2011 R2012 R2111 R2112 R2211 R2212 R2311 R2312 R2407 R2408 R2507 R2508 R2605 R2606 R2705 R2706 R2805 R2806 Group 29 discontinued Group 30 Group 31 Group 32 Group 33 Group 34 R3001 R3101 R3201 R3301 R3401 R3002 R3102 R3202 R3302 R3402 LEAP Atıksu ( Rev: Page 1 of 2

2 Numuneler atıksularda bulunan kontaminantların standart konsantratları veya ultra saf suda standart çözeltileridir. Grup 9 sertifikalı referans materyalidir. Aşağıdaki gruplar için testler mevcuttur: 1, 2, 3, 5, 6, 7, 8,10, 11, 12, 14, 15, 17, 18, 19, 20, 21, 22, 23, 24,25, 26, 27, 28 ve 29 numaralı gruplar analizden önce laboratuvarların su ile seyreltmesi gereken konsantratlardır. Sağlanan konsantratların hacimleri ve gereken seyreltme oranları aşağıda belirtilmiştir. 4, 9,13 ve 16 numaralı gruplar için seyreltme gerekmemektedir. 9'dan 29'a kadar olan gruplar için numuneler RTC, ABD tarafından sağlanmaktadır. Analyte Groups 1 BOD COD TOC 2 Dissolved Solids Suspended Solids Total Solids Settled COD 3 Nitrate (N) Nitrite (N) Ammonia (N) Chloride Orthophosphate (P) Sulphate (SO 4) Total Phosphorus (P) Kjeldahl Nitrogen (N) Total Nitrogen (N) 4 ph Electrical Conductivity 5 MBAS Alkylphenol Ethoxylates (APE) 6 Cyanide FREE Cyanide TOTAL mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l mg/l Units µs/cm mg/l mg/l mg/l mg/l 100 ml x ml x ml no dilution 7 Phenol (Monohydric by distillation) mg/l Sayfa 1 / 6

3 8 Cadmium Chromium Nickel Lead Copper Zinc Arsenic Selenium Mercury 9 Cadmium Lead Chromium Arsenic Barium Nickel Copper Zinc Mercury 10 Alkalinity Calcium Conductivity Total Hardness Magnesium Potassium Sodium 11 BOD COD TOC 12 Bromide Chloride Fluoride Sulphate mg/l mg/l mg/l mg/l mg/l mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg (as CaCO 3) mg/l mg/l µs/cm (as CaCO 3) mg/l 2 40 mg/l mg/l mg/l g no dilution 2 x 13 ph 5 10 ph units 100 ml No dilution 14 Ammonia (as N) Nitrate (as N) Orthophosphate (as P) 15 Kjeldahl Nitrogen (as N) Total Nitrogen (as N) Total Phosphorus 16 Total Solids Total Dissolved Solids Total Suspended Solids mg/l mg/l mg/l ml No dilution 26 Settleable Solids (tric test using Imhoff cone) ml/l 25 g to 1 L 17 Nitrite (as N) mg/l Sayfa 2 / 6

4 19 Hexavalent Chromium µg/l 20 Trace Metals 1 Aluminium Arsenic Beryllium Cadmium Chromium (Total) Cobalt Copper Iron Lead Manganese Mercury Nickel Selenium Vanadium Zinc µg/l Trace Metals 2 Antimony Barium Boron Molybdenum Silver Strontium Thallium µg/l Tin Titanium 18 Oil & Grease Suitable for EPA 1664, SM 5520B and other gravimetric methods. 23 Total Recoverable Petroleum Hydrocarbons Suitable for analysis by IR or gravimetric methods using Freon or Hexane extraction µg/L mg/l 3 ml to 1 L mg/l 3 ml to 1 L 24 Total Residual Chlorine mg/l 3 ml to 1 L 25 Total Sulphide 1 10 mg/l 3 ml to 1 L Sayfa 3 / 6

5 22 VOC 1 28 VOC 2 30 PAHs Benzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Ethylbenzene Methyl tert-butyl ether (MTBE) Naphthalene Toluene 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene m+p-xylene o-xylene Total Xylene Bromodichloromethane Bromoform Tetrachloromethane (carbon tetrachloride) Chlorobenzene Chloroform Dibromochloromethane 1,2-Dichloroethane Methylene Chloride (dichloromethane) Tetrachloroethene (tetrachloroethylene) 1,1,1-Trichoroethane Trichloroethene Acenaphthene Acenaphthylene Anthracene Benzo (a) anthracene Benzo (a) pyrene Benzo (b) fluoranthene Benzo (g,h,i) perylene Benzo (k) fluoranthene Chrysene Dibenz (a,h) anthracene Fluoranthene Fluorene Indeno (1,2,3-cd) pyrene Naphthalene Phenanthrene Pyrene µg/l µg/l ml to 100 ml 3 ml to 100 ml µg/l 3 ml to 1 L Sayfa 4 / 6

6 31 Pesticides minimum of 80% of the analytes listed Aldrin 4,4 -DDD 4,4 -DDE 4,4 -DDT Dieldrin Heptachlor Heptachlor Epoxide alpha-bhc beta- BHC delta-bhc gamma-bhc (Lindane) alpha-chlordane gamma-chlorodane Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Aldehyde Endrin Ketone Endrin Methoxychlor ug/l 2 x 3 ml to 1 L Sayfa 5 / 6

7 32 Dissolved Oxygen (Winkler) 1.0 to 100 mg/l 33 Diesel in Water 34 Gasoline in Water C9-C18 Aliphatic Hydrocarbons C19-C36 Aliphatic Hydrocarbons C9-C10 Aromatic Hydrocarbons C11-C22 Aromatic Hydrocarbons Diesel Range Organics (DRO) Diesel Range Organics C10-C28 Total EPH Benzene Ethylbenzene Methyl tert-butyl ether (MTBE) Naphthalene Toluene m+p-xylene o-xylene Xylene total C5-C8 Aliphatic Hydrocarbons C9-C12 Aliphatics C9-C10 Aromatic Hydrocarbons Gasoline Range Organics (GRO), C5-C12 Gasoline Range Organics (GRO), C6-C12 Gasoline Range Organics (GRO), C5-C10 Gasoline Range Organics (GRO), C6-C10 Total Purgeable Hydrocarbons 500 to 4000 ug/l 1.5 ml to 1 L ug/l 1.5 ml to 100 ml Sayfa 6 / 6