TÜRKAK TÜRK AKREDITASYON KURUMU TURKISH ACCREDITATION AGENCY tarafından akredıte edilmiştır. TÜV Rheinland Uluslararası Standartlar Sertıfıkasyon ve Denetım A.Ş. Saniye Ermutlu Sokak Çolakoğlu Plaza B Blok No: 12 KozyatağıISTANBUL Tel: 0 216 665 32 00 Fax: 0 216 665 32 99 emaıl : info@tr.tuv.com web: www.tr.tuv.com Deney Raporu Test report Müşterinin adı/adresi Costumer name/address YAKUT AYAKKABICILIK SARR.DERİC.LTD.ŞTİ / SARIYAKUP MAH. 23040 SOK. NO: 37/A ADANA Alıcı Adı Buyer name Sipariş/Artikel Numarası Order/Article No. Numunenin adı ve tarifi Name and identity of test item Numunenin kabul tarihi Date of receipt of test item Açıklamalar Remarks Proje tarihi Project date Raporun Sayfa Sayısı Number of pages of the Report Test Kapsamı Test Scope Ziylan Mağazacılık ve Pazarlama A.Ş. 6541429170123592382264926842706 / Kahve 2016 IY / Garamond / Yerli /41 / 42 20151210 The results given in this test report belong to the received sample by vendor. 20151211 20151217 9 SOP for Determination of Phthalates & Azo Dyes & Otin compounds Regulation dated 14/01/2015 duplicate issue 29236 Official journal Test Sonucu Test Result PASS Türk Akreditasyon kurumu (TÜRKAK) deney raporlarının tanınması konusunda Avrupa Akreditasyon Birliği (EA) ve Uluslar arası Laboratuar Akreditasyon Birliği (ILAC) ile karşılıklı tanınma anlaşmasını imzalamıştır. The Turkish Accreditation Acency (TÜRKAK) is signatory to the multilateral agreements of the European cooperation for the Accreditation (EA) and of the International Laboratory Accreditation (ILAC) for the Mutual recognation of the test reports. Deney ve /veya ölçüm sonuçları, genişletilmiş ölçüm belirsizlikleri (olması halinde) ve deney metodları bu sertifikanın tamamlayıcı kısmı olan takip eden sayfalarda verilmiştir. The test and/or measurement results, the uncertainties (if applicable) with confidence probability and test methods are given on the following, pages which are part of this report. Tarih Date Customer Relations Manager Organic Testing Team Leader 20151217 Tomris Hasançebi Kıvanç Karataş Bu rapor, laboratuvarın yazılı izni olmadan kısmen kopyalanıp çoğaltılamaz. Bu rapor eimza ile onaylanmıştır. This test report shall not be reproduced other than in full except with the permission of the laboratory. This test report is signed by e signature. Doc No: MS0010140_en / 20140702 Page 1 of 9 Version No / Date: 1.0
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Material List: Material No. Material Color Location Remark M001 Leather Ginger ShoesAUpper M002 Leather Lt.Brown ShoesCUpper M003 Leather Lt.Brown ShoesDUpper M004 Leather Brown ShoesBUpper;ShoesE Upper;ShoesFUpper M005 Leather Dk.Brown ShoesGUpper M006 Leather Brown ShoesHUpper M007 Leather Black ShoesECounter applique M008 Leather Brown ShoesAVamp lining M009 Leather + coating Dk.Brown/Transparent M010 Plastic Lt.Brown/Brown/Black/d k.grey ShoesBVamp lining w/glue;shoescvamp lining w/glue ShoesAOutsole w/print;shoesboutsole w/print;shoescoutsole w/print;shoeseoutsole w/print;shoesfoutsole w/print M011 Plastic + printing Black/Shiny Black ShoesATop piece w/print;shoesbtop piece w/print;shoesctop piece w/print;shoesdtop piece w/print;shoesetop piece w/print;shoesftop piece w/print M012 Leather + coating Brown/Transparent ShoesDInsock&lining w/glue M013 Plastic + printing Brown/LtBrown/Black/ ShoesDOutsole w/print;shoesgoutsole w/print;shoeshoutsole w/print M014 Leather Dk.Brown ShoesCTongue lining M015 Leather Brown ShoesDTongue lining M016 Leather Brown ShoesELining&insock M017 Textile Brown ShoesAShoe lace;shoesc Shoe lace;shoesdshoe lace M018 Textile Brown ShoesBElastic bant textile section;shoeseelastic bant textile section M019 Textile Brown ShoesACollar binding M020 Textile Brown ShoesESeam thread vamp thick M021 Textile Brown ShoesESeam thread on counter applique Page 3 of 9 N/A(<0,2)
M022 Textile Dk.Brown ShoesDSeam thread welt M023 Textile Brown ShoesHSeam thread vamp thick M024 Textile Dk.Brown ShoesGSeam thread vamp thick M025 Textile Dk.brown ShoesBSeam thread vamp&counter thick M026 Textile Dk.Brown ShoesBSeam thread on quarter thick M027 Textile Brown ShoesFSeam thread on quarter thick M028 Leather Brown ShoesFLining&insock M029 Leather Brown ShoesG Lining&insock;ShoesH Lining&insock M030 Leather Brown ShoesATongue lining M031 Leather + coating Brown/Transparent ShoesAVamp lining w/glue M032 Leather Brown ShoesALining insock M033 Leather Lt.Brown ShoesFLining&insock M034 Suede leather Lt.Brown ShoesACounter lining;shoesc Counter lining;shoesecounter lining M035 Suede leather Brown ShoesBCounter lining M036 Suede leather Beige ShoesDCounter lining M037 Suede leather Cream ShoesFCounter lining M038 Textile Brown ShoesASeam thread inside;shoesbseam thread inside;shoescseam thread inside;shoesdseam thread inside;shoeseseam thread inside;shoesgseam thread inside;shoeshseam thread inside M039 Textile Black ShoesFSeam thread thin inside M040 Textile Brown ShoesASeam thread thin upper;shoescseam thread thin upper;shoesdseam thread thin upper M041 Textile Brown ShoesBSeam thread thin upper;shoeseseam thread thin upper;shoesfseam thread thin upper;shoesgseam thread thin upper;shoesh Seam thread thin upper *Above articles have been described in accordance with the standard DIN EN 19952:2005. Page 4 of 9
1.Banned azo dyes Test Method: EN 143621:2012 (Textiles) ISO 172341:2010 (Leather) ISO 172342:2011 (Leather, 4aminoazobenzene confirmation) Test result: Test No. T001 T002 T003 T004 T005 Material No. M001 + M002 + M003 M004 + M005 + M006 M007 + M008 + M009 M012 + M014 + M015 M016 + M028 + M029 T006 M030 + M032 T007 M033 + M034 + M035 T008 M036 + M037 M017 + T009 M018 + M019 T010 M020 + M022 M023 + T011 M024 + M025 M001 + T012 M002 + M003 M007 + T013 M008 + M009 Test Parameter Method Unit RL Regulatory ISO 172341 mg/kg 10 30 ISO 172341 mg/kg 10 30 ISO 172341 mg/kg 10 30 ISO 172341 mg/kg 10 30 ISO 172341 mg/kg 10 30 Result and/or 1,4 and/or 1,4 and/or 1,4 and/or 1,4 and/or 1,4 ISO 172341 ISO 172341 mg/kg 10 30 and/or 1,4 ISO 172341 EN 143621 EN 143621 EN 143621 EN ISO 172342 (2011) (det. 4 EN ISO 172342 (2011) (det. 4 Page 5 of 9
Test Material No. No. M012 + T014 M014 + M015 M033 + T015 M034 + M035 M004 + T016 M005 + M006 M016 + T017 M028 + M029 Test Parameter Method Unit RL EN ISO 172342 (2011) (det. 4 EN ISO 172342 (2011) (det. 4 EN ISO 172342 (2011) (det. 4 EN ISO 172342 (2011) (det. 4 Abbreviation: n.d. = not detected (< Reporting Limit) RL = Reporting Limit mg/kg = milligram per kilogram Regulatory Result Page 6 of 9
Remark: * The CASnumber 97563 (A5) and 99558 (A6) are further reduced to CASnumber 95534 (A18) and 95807 (A19). ** Azo colorants that are able to form 4aminoazobenzene (A22) CASnumber 600903, generate under the condition of this method (A25) CASnumber 62533 and 4aminoaniline (A26) CASnumber 106503. *** Azo colorants that are able to form 4aminoazobenzene (A22), is confirmed by EN 143623:2012 / ISO 172342:2011. **** Azo colorants are detected & quantified by GC/MS and confirmed by LC/MS. ^ Additional azo colorants were tested according to customer's requirement. ID Azo colorant CAS No. ID Azo colorant CAS No. A1 biphenyl4ylamine / 4 aminobiphenyl / xenylamine 92671 A14 pcresidine 120718 A2 benzidine 92875 A15 4,4'methylenebis(2chloroaniline) / 2,2'dichloro4,4' methylenedianiline 101144 A3 4chlorootoluidine 95692 A16 4,4`oxydianiline 101804 A4 2naphthylamine 91598 A17 4,4`thiodianiline 139651 A5* oaminoazotoluene / 4amino2',3 dimethylazobenzene / 4otolylazootoluidine 97563 A18 otoluidine / 2aminotoluene 95534 A6* 5nitrootoluidine 99558 A19 4methylm amine 95807 A7 4chloroaniline 106478 A20 2,4,5trimethylaniline 137177 A8 4methoxym amine 615054 A21 oanisidine / 2methoxyaniline 90040 A9 A10 4,4'methylenedianiline / 4,4' diaminodiphenylmethane 3,3'dichlorobenzidine / 3,3' dichlorobiphenyl4,4'ylenediamine 101779 A22** 4aminoazobenzene 60093 91941 A23^ 2,4xylidine 95681 A11 3,3`dimethoxybenzidine 119904 A24^ 2,6xylidine 87627 A12 3,3'dimethylbenzidine / 4,4'biotoluidine 119937 A25^ 62533 A13 4,4`methylenediotoluidine 838880 A26^ 4aminoaniline 106503 Page 7 of 9
2.CPSIA Sect 108: Phthalates CPSIA Sect. 108 Phthalates PASS Test Method: CPSCCHC100109.3 Result: Test No. T001 T002 T003 Material No. M009 M010 M011 Test Parameter CAS NO Unit RL Regulatory Result Result Result Dibutyl phthalate 84742 % 0.005 0.1 n.d. n.d. n.d. (DBP) Benzylbutyl phthalate 85687 % 0.005 0.1 n.d. n.d. n.d. (BBP) Diethylhexyl 117817 % 0.005 0.1 n.d. n.d. n.d. phthalate (DEHP) Sum (DBP+BBP +DEHP) % 0.005 0.1 n.d. n.d. n.d. Test No. T004 T005 T006 Material No. M012 M013 M031 Test Parameter CAS NO Unit RL Regulatory Result Result Result Dibutyl phthalate 84742 % 0.005 0.1 n.d. n.d. n.d. (DBP) Benzylbutyl phthalate 85687 % 0.005 0.1 n.d. n.d. n.d. (BBP) Diethylhexyl 117817 % 0.005 0.1 n.d. n.d. 0.0187 phthalate (DEHP) Sum (DBP+BBP +DEHP) % 0.005 0.1 n.d. n.d. 0.0187 Abbreviation: Abbreviation n.d. = Not Detected (< RL) RL = Reporting Limit % denotes percentage Page 8 of 9
3.Organotin Compounds (DOT) Test Method: Organic solvent extraction, GCMS MS_0009932tr Test No. T001 T002 Material No. M017 + M018 + M022 + M023 M019 Test Parameter Unit RL Regulatory Result Result DOT(Dioctyltin) % 0.01 0.1 n.d. n.d. Abbreviation: n.d. = not detected (< Reporting Limit) RL = Reporting Limit % = percentage NA = Not Applicable *1 Single components with an amount of <0.01% were not considered in the calculation of the sum. In the case of all five trisubstituted organotins were not detected, the result is stated n.d. *2 The assessment for trisubstituted organotins is based on the sum of TBT, TPT, TOT, TCyT and TPrT only. *3 According to REACH Regulation (EC) No. 1907/2006 Annex XVII Item 20 and amendment Commission Regulation (EU) No. 276/2010 (formerly known as 2009/425/EC), organostannic compounds shall not be used or be placed on the market END Page 9 of 9