TÜRKAK TÜRK AKREDITASYON KURUMU TURKISH ACCREDITATION AGENCY tarafından akredıte edilmiştır. TÜV Rheinland Uluslararası Standartlar Sertıfıkasyon ve Denetım A.Ş. Saniye Ermutlu Sokak Çolakoğlu Plaza B Blok No: 12 Kozyatağı-ISTANBUL Tel: 0 216 665 32 00 - Fax: 0 216 665 32 99 emaıl : info@tr.tuv.com web: www.tr.tuv.com Deney Raporu Test report Müşterinin adı/adresi Costumer name/address YAKUT AYAKKABICILIK SARR.DERİC.LTD.ŞTİ / SARIYAKUP MAH. 23040 SOK. NO: 37/A ADANA Alıcı Adı Buyer name Sipariş/Artikel Numarası Order/Article No. Numunenin adı ve tarifi Name and identity of test item Numunenin kabul tarihi Date of receipt of test item Açıklamalar Remarks Proje tarihi Project date Raporun Sayfa Sayısı Number of pages of the Report Test Kapsamı Test Scope Ziylan Mağazacılık ve Pazarlama A.Ş. 2685 / Kahve-Taba-Lacivert 2016 IY / Cordovan / Yerli / 41 / 42 2015-12-10 The results given in this test report belong to the received sample by vendor. 2015-12-11-2015-12-17 7 SOP for Determination of Phthalates & Azo Dyes & O-tin compounds Regulation dated 14/01/2015 duplicate issue 29236 Official journal Test Sonucu Test Result PASS Türk Akreditasyon kurumu (TÜRKAK) deney raporlarının tanınması konusunda Avrupa Akreditasyon Birliği (EA) ve Uluslar arası Laboratuar Akreditasyon Birliği (ILAC) ile karşılıklı tanınma anlaşmasını imzalamıştır. The Turkish Accreditation Acency (TÜRKAK) is signatory to the multilateral agreements of the European co-operation for the Accreditation (EA) and of the International Laboratory Accreditation (ILAC) for the Mutual recognation of the test reports. Deney ve /veya ölçüm sonuçları, genişletilmiş ölçüm belirsizlikleri (olması halinde) ve deney metodları bu sertifikanın tamamlayıcı kısmı olan takip eden sayfalarda verilmiştir. The test and/or measurement results, the uncertainties (if applicable) with confidence probability and test methods are given on the following, pages which are part of this report. Tarih Date Customer Relations Manager Organic Testing Team Leader 2015-12-17 Tomris Hasançebi Kıvanç Karataş Bu rapor, laboratuvarın yazılı izni olmadan kısmen kopyalanıp çoğaltılamaz. Bu rapor e-imza ile onaylanmıştır. This test report shall not be reproduced other than in full except with the permission of the laboratory. This test report is signed by e- signature. Doc No: MS-0010140_en / 2014-07-02 Page 1 of 7 Version No / Date: 1.0
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Material List: Material No. Material Color Location Remark M001 Leather Ginger Shoe A-Upper - M002 Leather Navy ShoeB-Upper;ShoeC-Upper - M003 Leather Bordeaux Upper(c) - M004 Leather Dk.Brown Shoe A-Lining - M005 Leather Red ShoeB-Upper&insock - M006 Leather Bordeaux ShoeC-Upper&insock - M007 Leather Brown Shoe A-Insock - M008 Suede leather Dk.Brown Shoe A-Counter lining - M009 Suede leather Lt.Blue ShoeB-Counter lining - M010 Plastic White Shoe A-Outsole;ShoeB- Outsole;ShoeC-Outsole M011 Plastic Brown/Dk.Brown Shoe A-Midsole binding - M012 Plastic Navy/Yellow ShoeB-Midsole binding - M013 Plastic Navy/Bordeaux ShoeC-Midsole binding - M014 Textile Brown Shoe A-Seam thread upper thick M015 Textile Navy ShoeB-Seam thread upper thick - M016 Textile Bordeaux ShoeC-Seam thread upper thick M017 Textile Welt Shoe A-Seam thread welt;shoeb-seam thread welt;shoec-seam thread welt - - - N/A(<0,2g) M018 Textile Brown Shoe A-Seam thread upper thin N/A(<0,2g) M019 Textile Navy ShoeB-Seam thread upper thin N/A(<0,2g) M020 Textile Bordeaux ShoeC-Seam thread upper thin N/A(<0,2g) M021 Textile Brown Shoe A-Seam thread inside thin N/A(<0,2g) M022 Textile Black ShoeB-Seam thread inside thin N/A(<0,2g) M023 Textile Black ShoeC-Seam thread inside thin N/A(<0,2g) *Above articles have been described in accordance with the standard DIN EN 19952:2005. Page 3 of 7
1.Banned azo dyes Test Method: EN 14362-1:2012 (Textiles) ISO 17234-1:2010 (Leather) ISO 17234-2:2011 (Leather, 4-aminoazobenzene confirmation) Test result: Test Material No. No. M001 + T001 M002 + M003 T002 T003 T004 T005 T006 M004 + M005 + M006 M007 + M008 + M009 M014 + M015 + M016 M004 + M005 + M006 M008 + M007 + M009 Test Parameter Method Unit RL Regulatory Requirement Result Azo dyes ISO 17234-1 mg/kg 10 30 n.d. Azo dyes ISO 17234-1 mg/kg 10 30 Azo dyes ISO 17234-1 mg/kg 10 30 Aniline and \or 1.4- phenylenedi amine are detected Aniline and \or 1.4- phenylenedi amine are detected Azo dyes EN 14362-1 mg/kg 10 30 n.d. Azo dyes Azo dyes EN ISO 17234-2 (2011) (det. 4- aminoazobenzene) EN ISO 17234-2 (2011) (det. 4- aminoazobenzene) Abbreviation: n.d. = not detected (< Reporting Limit) RL = Reporting Limit mg/kg = milligram per kilogram mg/kg 10 30 n.d. mg/kg 10 30 n.d. Page 4 of 7
Remark: * The CAS-number 97-56-3 (A5) and 99-55-8 (A6) are further reduced to CAS-number 95-53-4 (A18) and 95-80-7 (A19). ** Azo colorants that are able to form 4-aminoazobenzene (A22) CAS-number 60-09-03, generate under the condition of this method Aniline (A25) CAS-number 62-53-3 and 4-aminoaniline (A26) CASnumber 106-50-3. *** Azo colorants that are able to form 4-aminoazobenzene (A22), is confirmed by EN 14362-3:2012 / ISO 17234-2:2011. **** Azo colorants are detected & quantified by GC/MS and confirmed by LC/MS. ^ Additional azo colorants were tested according to customer's requirement. ID Azo colorant CAS No. ID Azo colorant CAS No. A1 biphenyl-4-ylamine / 4- aminobiphenyl / xenylamine 92-67-1 A14 p-cresidine 120-71-8 A2 benzidine 92-87-5 A15 4,4'-methylene-bis-(2-chloroaniline) / 2,2'-dichloro-4,4'- methylene-dianiline 101-14-4 A3 4-chloro-o-toluidine 95-69-2 A16 4,4`-oxydianiline 101-80-4 A4 2-naphthylamine 91-59-8 A17 4,4`-thiodianiline 139-65-1 A5* o-aminoazotoluene / 4-amino-2',3- dimethylazobenzene / 4-o-tolylazoo-toluidine 97-56-3 A18 o-toluidine / 2-aminotoluene 95-53-4 A6* 5-nitro-o-toluidine 99-55-8 A19 4-methyl-m- phenylenediamine 95-80-7 A7 4-chloroaniline 106-47-8 A20 2,4,5-trimethylaniline 137-17-7 A8 4-methoxy-m- phenylenediamine 615-05-4 A21 o-anisidine / 2-methoxyaniline 90-04-0 A9 A10 4,4'-methylenedianiline / 4,4'- diaminodiphenylmethane 3,3'-dichlorobenzidine / 3,3'- dichlorobiphenyl-4,4'-ylenediamine 101-77-9 A22** 4-aminoazobenzene 60-09-3 91-94-1 A23^ 2,4-xylidine 95-68-1 A11 3,3`-dimethoxybenzidine 119-90-4 A24^ 2,6-xylidine 87-62-7 A12 3,3'-dimethylbenzidine / 4,4'-bi-otoluidine 119-93-7 A25^ Aniline 62-53-3 A13 4,4`-methylenedi-o-toluidine 838-88-0 A26^ 4-aminoaniline 106-50-3 Page 5 of 7
2.CPSIA Sect 108: Phthalates CPSIA Sect. 108 Phthalates PASS Test Method: CPSC-CH-C1001-09.3 Result: Test No. T001 T002 T003 Material No. M010 + M012 M013 M011 Test Parameter CAS NO Unit RL Regulatory Result Result Result Requirement Dibutyl phthalate 84-74-2 % 0.005 0.1 n.d. n.d. n.d. (DBP) Benzylbutyl phthalate 85-68-7 % 0.005 0.1 n.d. n.d. n.d. (BBP) Diethylhexyl 117-81-7 % 0.005 0.1 n.d. n.d. n.d. phthalate (DEHP) Sum (DBP+BBP +DEHP) - % 0.005 0.1 n.d. n.d. n.d. Abbreviation: Abbreviation n.d. = Not Detected (< RL) RL = Reporting Limit % denotes percentage Page 6 of 7
3.Organotin Compounds ( DOT) Test Method: Organic solvent extraction, GCMS MS_0009932-tr Test No. T001 Material No. M014 + M015 + M016 Test Parameter Unit RL Regulatory Result Requirement DOT(Dioctyltin) % 0.01 0.1 n.d. Abbreviation: n.d. = not detected (< Reporting Limit) RL = Reporting Limit % = percentage NA = Not Applicable *1 Single components with an amount of <0.01% were not considered in the calculation of the sum. In the case of all five tri-substituted organotins were not detected, the result is stated n.d. *2 The assessment for tri-substituted organotins is based on the sum of TBT, TPT, TOT, TCyT and TPrT only. *3 According to REACH Regulation (EC) No. 1907/2006 Annex XVII Item 20 and amendment Commission Regulation (EU) No. 276/2010 (formerly known as 2009/425/EC), organostannic compounds shall not be used or be placed on the market- - END - Page 7 of 7