. T.C. INTERTEK TEST HİZMETLERİ A.Ş. INTERTEK MUAYENE VE ANALİZ RAPORU EXAMINATION & ANALYSIS REPORT Rapor No/ Report No: MS10012148 Tarih/ Date: 19/01/2018 Analizin Amacı/ Purpose of Analysis: Özel İstek / Private Demand Müşteri Bilgiler / Customer Information Müşteri Adı / Customer Name Adres / Address Özgür Tarım Ürün.İnşaat Sanayi ve Tic.A.Ş. Istasyon Mh.Kuvayi Milliye Cd.No:7,, Saruhanli, Manisa, TURKEY, Numune Bilgileri / Sample Information Adı / Name Çekirdeksiz Kuru Üzüm / Seedless Raisins Üretici Adı / Producer Name Tanımı ve Seri - Parti No / Description and Batch Number 14-0131 Üretim ve Son Kullanma Tarihi / Production & Expiry Date Ambalajı ve Miktarı / Package and Quantity İlgili Kişi / Contact Person Numune kabul tarihi / Sample received / transport by Numune alım sıcaklığı / Sample temp when received Numuneyi teslim alan ve mühür / Submitted by & Seal Teklif No / Quotation No Analiz başlama ve bitiş zamanı / Start / End of analysis 1x1 kg kilitli poşet / zipped package Bilge Üstünkaya [bilgeustunkaya@ozgurtarim.com.tr] 19/01/2018 yerinde teslim / submitted on site +16 C Müşteri Mühürsüz / Client None 19.01.2018 / 19.01.2018 Açıklamalar / Remarks Fatma Bayram Numune Kabul ve Raporlama Birim Sorumlusu / Supervisor of Sample Receiving and Reporting Section Betül Şakrak Kimyasal Analiz Laboratuvar Sorumlusu / Supervisor of Chemical Analysis Laboratory 19/01/2018 Tasdik Olunur / Approved by Laboratuvar Müdürü / Laboratory Manager Ayşe Eren Ok Form FD.058 / Rev.3/02.05.2017 Bu analiz raporu adli -idari işlemlerde ve reklam amacıyla kullanılamaz.bu analiz raporunun hiçbir bölümü laboratuvarın yazılı izni olmadan kısmen kopyalanıp, cogaltilamaz, tek başına veya ayrı ayrı kullanılamaz. Analiz sonuçları yukarıda belirtilen numune için geçerlidir. İmzasız ve mühürsüz raporlar geçersizdir. The whole and/or the part of this report shall not be reproduced and shall not be shared with third parties, nor to be used for juridical - official and PR activities without the written permission of INTERTEK Test Hizmetleri A.S. The results given herein apply to the submitted sample only. Reports are invalid without signature and seal. Intertek Test Hizmetleri A.Ş. 75. Yıl Mah. Bahri Sarıtepe Cad. No:13 Manisa/ TÜRKİYE web: http://www.intertekfoodturkey.com/ Tel : 0 236 302 00 00 Faks : 0 236 302 00 01 e-mail: intertek.turkey@hs01.kep.tr, foodlab.turkey@intertek.com *MS10012148* Sayfa / Toplam Sayfa 1/2 Page / Total Pages
. T.C. INTERTEK TEST HİZMETLERİ A.Ş. INTERTEK MUAYENE VE ANALİZ RAPORU EXAMINATION & ANALYSIS REPORT Rapor No/ Report No: MS10012148 Tarih/ Date: 19/01/2018 Analizler / Analyses No Analiz Adı Analysis Name Sonuç Results Ölçüm Limiti LOQ Geri Kazanım Recovery Ölçüm Belirsizliği Uncertainty Metot Method Limit Requirement Değerlendirme Interpretation 1 Seçilmiş Bazı Pestisitlerin Tespit Edilemedi/ 0,01 - - AOAC 2007.01 <= a Tespiti ve Miktarının Not Detected Belirlenmesi Analizi GC/MS Method* Determination of Detection and Quantitative Analysis of Selected Pesticides* Seçilmiş Bazı Pestisitlerin - 1 - - AOAC 2007.01 <= a Tespiti ve Miktarının Belirlenmesi Analizi LC/MSMS Method (Shimadzu 8040)* Determination of Detection and Quantitative Analysis of Selected Pesticides* 2 Cyprodinil* 0,041 - ±0,021 AOAC 2007.01 <= 3 b Cyprodinil* 3 Indoxacarb (Sum)* 0,017 - ±0,009 AOAC 2007.01 <= 2 c Indoxacarb (Sum)* LOQ: Ölçüm Limiti / Limit of Quantification LOD: Tespit Limiti / Limit of Detection *İşaretli analiz Turkak akreditasyon kapsamındadır. / *Marked analysis is in scope of Turkak accreditation (±) k=2, % 95 güven araliginda genisletilmis ölçüm belirsizligi ile raporlandirilmistir. / The reported uncertainty is an expanded uncertainty calculated using a coverage factor of 2 which gives a level of confidence of approximately 95%. 1 Analiz edilen pestisit listesinde tespit edilen sonuçlar bu raporda sunulmuştur./detected and tested pesticides list are published in this report. a EU MRL :Avrupa Maksimum Kalıntı Limitleri (Yönetmelik(EC) No 396/2005) / EU MRLs: European Maximum Residue Limits (Regulation (EC) No 396/2005) b EU MRL :Avrupa Maksimum Kalıntı Limitleri (Yönetmelik(EC) No 396/2005)(Üzüm) / EU MRLs: European Maximum Residue Limits (Regulation (EC) No 396/2005)(Raisin) c EU MRL :Avrupa Maksimum Kalıntı Limitleri (Yönetmelik(EC) No 396/2005)(Üzüm)/ EU MRLs: European Maximum Residue Limits (Regulation (EC) No 396/2005)(Grape) Fatma Bayram Numune Kabul ve Raporlama Birim Sorumlusu / Supervisor of Sample Receiving and Reporting Section Betül Şakrak Kimyasal Analiz Laboratuvar Sorumlusu / Supervisor of Chemical Analysis Laboratory 19/01/2018 Tasdik Olunur / Approved by Laboratuvar Müdürü / Laboratory Manager Ayşe Eren Ok Form FD.058 / Rev.3/02.05.2017 Bu analiz raporu adli -idari işlemlerde ve reklam amacıyla kullanılamaz.bu analiz raporunun hiçbir bölümü laboratuvarın yazılı izni olmadan kısmen kopyalanıp, cogaltilamaz, tek başına veya ayrı ayrı kullanılamaz. Analiz sonuçları yukarıda belirtilen numune için geçerlidir. İmzasız ve mühürsüz raporlar geçersizdir. The whole and/or the part of this report shall not be reproduced and shall not be shared with third parties, nor to be used for juridical - official and PR activities without the written permission of INTERTEK Test Hizmetleri A.S. The results given herein apply to the submitted sample only. Reports are invalid without signature and seal. Rapor Sonu / End of Report Intertek Test Hizmetleri A.Ş. 75. Yıl Mah. Bahri Sarıtepe Cad. No:13 Manisa/ TÜRKİYE web: http://www.intertekfoodturkey.com/ Tel : 0 236 302 00 00 Faks : 0 236 302 00 01 e-mail: intertek.turkey@hs01.kep.tr, foodlab.turkey@intertek.com *MS10012148* Sayfa / Toplam Sayfa 2/2 Page / Total Pages
GC / MSD ANALİZLENEN PESTİSİT LİSTESİ THE LIST OF ANALYSED GC / MSD GROUP PESTICIDES LOQ DEGERLERİ& LOQ S VALUES ( 0.010 ) 1. 0-Chloraniline 25. Chlorbenside 49. Dicofol ( sum ) 73. Fenvalerate ( sum) 97. Isodrin 121. Propham 2. 2,4-DDD 26. Chlorbenzilate 50. Dieldrin 74. Fenvalerate I 98. Isoxaben 122. Propiconazole I 3. 2,4-DDE 27. Chlorfenapry 51. Diethyltoluamide DEET 75. Fenvalerate II 99. Leptophos 123. Propiconazole II 4. 2,4-DDT 28. Chlorfenson 52. Diflubenzuron 76. Esfenvalerate+Fenvalerate(sum) 100. Methacrifos 124. Propiconozole(Sum) 5. 2-phenyl phenol 29. Chloroneb 53. Dinobuton 77. Fluchloralin 101. Methidathion 125. Quinalphos 6. 3,4,5 Trimethocarb 30. Chlorpropham 54. Diphenlyamine 78. Flucythrinate (sum) 102. Methoxychlor 126. Quinomethionate( Chinomethionate) 7. 4,4-DDD 31. Chlortal-dimethyl(DCPA) 55. Diphenylmercury 79. Flucythrinate I 103. Mirex 127. Quinoxyfen 8. 4,4-DDE 32. Chlorothalonil 56. Endosulfan ( sum ) 80. Flucythrinate II 104. Nitrapyrin 128. Silofluofen 9. 4,4-DDT 33. Chlozolinate 57. Endosulfan alpha 81. Fluotrimazole 105. Nitrothal-Isopropyl 129. Tebuconazole 10. Aclonifen 34. Chlorantraniliprole 58. Endosulfan beta 82. Fluquinconazole 106. Nitrofen 130. Tecnazane 11. Aldrin 35. Clodinafop propargyl ester 59. Endosulfan sulfate 83. Folpet 107. Oxyflourfen 131. Teflubenzuron 12. Amitraz 36. Cyfluthrin (sum) 60. Endrin 84. Formothion 108. Parathion (sum) 132. Tefluthrin 13. Barban 37. Cyfluthrin I 61. Esfenvalerate (sum) 85. Gama cyhalothrin 109. Parathion ethyl 133. Terbacil 14. Benfluralin 38. Cyfluthrin II 62. Esfenvalerate I 86. HCH (sum) 110. Parathion methyl 134. Tetraconazole 15. Bioresmethrin 39. Cyfluthrin III 63. Esfenvalerate II 87. HCH-Alpha 111. PCNB ( Quintozone ) 135. Tetradifon 16. Biphenyl 40. Cyfluthrin IV 64. Ethalfluralin 88. HCH-Beta 112. Pebulate 136. Tetrasul 17. Bitertanol 41. Cyhalofop buthyl 65. Ethofumesate 89. HCH-Delta 113. Pentachloroanisole 137. Thiafonox 18. Bromociclen 42. Cypermethrin ( sum ) 66. Ethoprophos 90. HCH-Gama 114. Pentacholoaniline 138. Transfluthrin 19. Bromophos ethyl 43. Cypermethrin I 67. Etridiazole 91. Hekzachlorobenzen 115. Perthane 139. Trifluralin 20. Bromophos methyl 44. Cypermethrin II 68. Fenarimol 92. Heptachlor ( sum ) 116. Phorate 140. Vinclozolin 21. Bromopropylate 45. Cypermethrin III 69. Fenchlorphos 93. Heptachlor 117. Primicarb dimethyl formomido 141. Zoxamide 22. Captafol 46. Cypermethrin IV 70. Fenithrothion 94. Heptachlor endo epoxide 118. Procymidone 23. Captan 47. Diclobenil 71. Fenson 95. Heptachlor exo epoxide 119. Profluralin 24. Carbophenothion 48. Dichlofenthion 72. Fenthion 96. Iodofenphos(lodophos) 120. Propetamphos 1) Bu lisetede yer alan tüm pestisitlerin LOQ değerleri 0.010 dır./loq value of all pesticides in this list of 0.010. Bu liste 1 sayfadan ibarettir. EK- A
LC-MS / MS ANALİZLENEN PESTİSİT LİSTESİ THE LIST OF ANALYSED LC-MS / MS GROUP PESTICIDES LOQ DEGERLERİ& LOQ S VALUES( 0.005 ) 1 2,4,5 T 2 24D 3 Abamectin 4 Acephate 5 Acetamiprid 6 Acetochlor 7 Acrinathrin 8 Alachlor 9 Aldicarb 10 Aldicarb Sulfoxide 11 AldicarbSulfone 12 Allethrin 13 Ametoctradin 14 Ametryn 15 Aminocarb 16 Aramit 17 Atrazine 18 Avermectin B1A 19 Azimsulfuron 20 Azinphos-ethyl 21 Azinphos-methyl 22 Aziprotyne 23 Azocanazole 24 Azoxystrobin 25 Benalaxyl 26 Bendiocarb 27 Benflubutamid 28 Benfuracarb 29 Bensulfuron methyl 30 Bentazone 31 Benthiovalicarb-isopropyl 32 Bifenazate 33 Bifenthrin 34 Bitertanol 35 Boscalid 36 Bromacil 37 Bromoxynil 38 Bromuconazole 39 Buprimate 40 Buprofezin 41 Butafenacil 42 Butamifos 43 Butocarboxim 44 Butocarboxim sulfoxide 45 Butralin 46 Buturon 47 Cadusafos 48 Carbaryl 49 Carbendazim(Benomyl) 50 Carbofuran 51 Carbofuran-3-hidroxy 52 Carbosulfan 53 Carboxin 54 Carfentrazone ethyl 55 Chlofentezine 56 Chlorbromuron 57 Chlorbufam 58 Chlorfenvinhos 59 Chlorfluazuron 60 Chloridazon 61 Chlormequat Chloride 62 Chloropyrifos Methyl 63 Chlorotoloron 64 Chloroxuron 65 Chlorpyrifos 66 Cinidon Ethyl 67 Clethodim 68 Climbazole 69 Clodinafop 70 Clomazone 71 Cloquintocet-1-mexylhexylester 72 Clothianidine 73 Coumaphos 74 Crimidine 75 Crotoxyphos 76 Cyanafenphos 77 Cyazofamid 78 Cyclanilide 79 Cycloate 80 Cycloxydim 81 Cyflufenamid 82 Cyhexatin 83 Cymoxanil 84 Cypermethrin 85 Cyphenothrin 86 Cyproconazole 87 Cyprodinil 88 Cyromazine 89 Daminozide 90 Deltamethrin 91 Demeton-s-methyl 92 Demeton-s-methyl sulfone 93 Desmedipham 94 Desmetryn 95 Diafenthiuron 96 Dialifos 97 Di-allate 98 Diazinon 99 Dicamba 100 Dichlofluanid 101 Dichlorprop-P 102 Dichlorvos DDVP 103 Diclobutrazol 104 Diclofop Methyl 105 Dicrotophos 106 Diethofencarb 107 Difenacozole 108 Difenoxuron 109 Diflufenican 110 Diflufenzopyr pos 111 Dimefuron 112 Dimethachlor 113 Dimethenamid 114 Dimethoate 115 Dimethomorph 116 Dimethylvinphos 117 Dimoxystrobin 118 Diniconazole 119 Dinitramine 120 Dinocap 121 Dinoseb 122 Dinoterb 123 Dioxacarb 124 Dioxathion 125 Diphenamid 126 Dipropetryn 127 Disulfoton 128 Disulfoton sulfone 129 Disulfoton sulfoxide 130 Ditalimfos 131 Dithianon 132 Diuron 133 DMST 134 DNOC 135 Dodine 136 Edifenphos 137 E-Fenproxymate 138 Emamectin B1A 139 Emamectin B1B 140 Epoxiconazole 141 EPTC 142 Esfenvalerate 143 Etaconazole 144 Ethiofencarb 145 Ethiofencarb sulfone 146 Ethiofencarb sulfoxide 147 Ethion 148 Ethirimol 149 Ethofumesata 150 Ethoxyquin 151 Etofenprox 152 Etoxazole 153 Etrimfos 154 Famaxadone 155 Famphur 156 Fenamidone 157 Fenamiphos 158 Fenamiphos sulfone 159 Fenamiphos sulfoxide 160 Fenarimol 161 Fenazaquin 162 Fenbuconazole 163 Fenbutatin oxide 164 Fenchlorazol ethyl 165 Fenchlorphos oxon 166 Fenhexamide 167 Fenobucarb 168 Fenoprop(2,4,5 TP) 169 Fenoxaprop-P-ethyl 170 Fenoxycarb 171 Fenpiclonil 172 Fenpropathrin 173 Fenpropidin 174 Fenpropimorph 175 Fenproximate 176 Fensulfothion 177 Fensulfothion oxon 178 Fensulfothion oxon sulfone 179 Fensulfothion sulfone 180 Fenthion 181 Fenthion oxon 182 Fenthion oxon sulfone 183 Fenthion oxon sulfoxide 184 Fenthion sulfone 185 Fenthion sulfoxide 186 Fenvalerate 187 Fipronil 188 Fipronil desulfinyl 189 Fipronil sulfone 190 Florasulam 191 Fluazifop- P-Buthyl 192 Fluazifop-P 193 Fluazinam 194 Flubendiamide 195 Fludioxinil 196 Flufenacet 197 Flufenoxuron 198 Flumeturon 199 Flumioxazin 200 Flunicamid 201 Fluopicolide 202 Fluopyram 203 Flupyrsulfuron-methyl sodium 204 Fluquinconazole 205 Flurochloridone 206 Fluroxypr 207 Flurprimidol 208 Flusilazole 209 Fluthiacet methyl 210 Flutolanil 211 Flutriafol 212 Fonofos 213 Foramsulfuron 214 Forchlorfenuron 215 Formetanete Hydrochloride 216 Fosthiazate 217 Fuberidazole 218 Furalaxyl 219 Furathiocarb 220 Halfenprox 221 Haloxyfop 222 Haloxyfop-2-etoxy ethyl 223 Heptenophos 224 Hexaconazole 225 Hexaflumuron 226 Hexazinone 227 Hexythiazox 228 Imazalil 229 Imazapic 230 Imazapyr 231 Imazaquin 232 Imazethapyr 233 Imibenconazole 234 Imibenconazole 235 Imidachloropid 236 Indoxacarb 237 Iodosulfuron methyl sodium 238 Ioxynil 239 Iprobenfos 240 Iprodion 241 Iprovalicarb 242 Isazofos 243 Isocarbofos 244 Isofenphos 245 Isofenphos oxon 246 Isofenphos-methyl 247 Isoprocarb 248 Isoprothiolane 249 Isoproturon 250 Isoxaben 251 Isoxadifen ethyl 252 Isoxaflutole 253 Isoxathion 254 Kresoxim Methyl 255 Lambda-cyhalothrin 256 Lenacil 257 Linuron 258 Lufenuron 259 Malaoxon 260 Malathion 261 Mandipropamid 262 MCPA 263 Mecarbam 264 Mecoprop (MCPP) 265 Mefenpyr-diethyl 266 Mepanipyrim 267 Mepanipyrim-2-hydroxypropyl 268 Mepiquat chloride 269 Mepronil 270 Meptyldinocap 271 Mesotrione 272 Metaflumizone 273 Metalaxyl 274 Metalaxyl Methyl 275 Metamitron 1) **İşaretli etken maddeler Türkak Akreditasyon kapsamında değildir / **Marked active substance is not in scope of Türkak Accreditation 2) Bu lisetede yer alan tüm pestisitlerin LOQ değerleri 0.005 dır.loq value of all pesticides in this list of 0.005. Bu liste 2 sayfadan ibarettir. EK- C
LC-MS / MS ANALİZLENEN PESTİSİT LİSTESİ THE LIST OF ANALYSED LC-MS / MS GROUP PESTICIDES LOQ DEGERLERİ& LOQ S VALUES( 0.005 ) 276 Metasulam 277 Metazachlor 278 Metconazole 279 Methabenzthiazuron 280 Methamidophos 281 Methiocarb 282 Methiocarb Sulfone 283 Methiocarb Sulfoxide 284 Methomyl 285 Methoprotryne 286 Methoprotryne 287 Methoxyfenozide 288 Methyl pentachlorphenyl sulfide 289 Metolachlor 290 Metolcarb 291 Metoxuron 292 Metrofenone 293 Metrubuzin 294 Metsulfuron-methyl 295 Mevinphos 296 Molinate 297 Monocrotophos 298 Monolinuron 299 Monuron 300 Myclobutanil 301 Napropiamide 302 Naptalam 303 Neburon 304 Nicosulfuron 305 Nitenpyram 306 Nitralin 307 Norfluazuron 308 Novaluron 309 Ofurace 310 Omethoate 311 OO-TEPP 312 Oxadixyl 313 Oxamyl 314 Demeton-s-methysulfoxide 315 Paclabutrazol 316 Paraoxon-ethyl 317 Paraoxon-methyl 318 Penconazole 319 Pencycuron 320 Permethrin 321 Pethoxamid 322 Phendimethalin 323 Phenthoate 324 Phorate sulfone 325 Phorate sulfoxide 326 Phosalone 327 Phosmet 328 Phosmet oxon 329 Phosphamidon 330 Phoxim 331 Picolinafen 332 Picoxystrobin 333 Pirimicarb-Desmethyl 334 Pirimicarb-Desmethyl-Formomido 335 Pirimiphos-methyl 336 Primicarb 337 Primiphos Ethyl 338 Primiphos methyl N-desethyl 339 Prochloraz 340 Profenefos 341 Profoxydim-lithium 342 Promecarb 343 Prometon 344 Prometryn 345 Propachlor 346 Propamocarb 347 Propaquizafob 348 Propargite 349 Propazine 350 Propethamphos 351 Propiconozole 352 Propoxur 353 Propoxycarbazone sodium 354 Propyzamide 355 Proquinazid 356 Prosulfocarb 357 Prosulfuron 358 Prothioconazole 359 Prothioconazole desthio 360 Prothiophos 361 Pymetrozine 362 Pyraclostrobin 363 Pyrafluorfen-ethyl 364 Pyrazophos 365 Pyridaben 366 Pyridalyl 367 Pyridaphenthion 368 Pyridate 369 Pyrifenox 370 Pyrimethanil 371 Pyriproxypen 372 Quinalphos 373 Quinmerac 374 Quinoxyfen 375 Quizalafop 376 Rimsulfuron 377 Rotenone 378 Sethoxydim 379 Siduron 380 Silofluofen 381 Silthiafam 382 Simazine 383 Simetryn 384 S-Metalachlor 385 Spinetoram 386 Spinosyn A 387 Spinosyn D 388 Spirodiclofen 389 Spiromesifen 390 Spirotetramat 391 Spirotetramat enol 392 Spirotetramat enol glocoside 393 Spirotetramat keto hydroxy 394 Spirotetramat monohydroxy 395 Spiroxamine 396 Sulcotrione 397 Sulfosulfuron 398 Sulfotep 399 Sulprofos 400 Tau-Fluvalinate 401 Tebuconazole 402 Tebufenozide 403 Tebufenpyrad 404 Teflubenzuron 405 Tepraloxydim 406 Terbufos 407 Terbufos sulfone 408 Terbufos sulfoxide 409 Terbumeton 410 Terbutryn 411 Terbutylazine 412 Tetrachlorvinphos 413 Tetramethrin 414 Thiabendazole 415 Thiacloprid 416 Thiamethoxam 417 Thiaphionat Methyl 418 Thiazafluron 419 Thifensulfuron-methyl 420 Thiobencarb 421 Thiodicarb 422 Thiofanox sulfone 423 Thiofanox sulfoxide 424 Thiofonox 425 Thiometon 426 Thionazin 427 Thiram** 428 Tolclofos methyl 429 Tolyfluanid 430 Tralkoxydim 431 Triadimefon 432 Triadimenol 433 Triallate 434 Triamiphos 435 Triasulfuron 436 Triazamate 437 Triazophos 438 Tribenuron methyl 439 Trichlorfon 440 Tricyclazole 441 Tridemorph 442 Trifloxystrobin 443 Triflumizole 444 Triflumuron 445 Triforine 446 Triticonazole 447 Uniconazole 448 Vamidathion 1) **İşaretli etken maddeler Türkak Akreditasyon kapsamında değildir / **Marked active substance is not in scope of Türkak Accreditation 2) Bu lisetede yer alan tüm pestisitlerin LOQ değerleri 0.005 dır.loq value of all pesticides in this list of 0.005. Bu liste 2 sayfadan ibarettir. EK- C