Assoc. Prof. Dr. MELİKE (KOÇOĞLU) KALKAN S BIOGRAPHICAL SUMMARY

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1 Assoc. Prof. Dr. MELİKE (KOÇOĞLU) KALKAN S BIOGRAPHICAL SUMMARY Ankara University Faculty of Science Dept. of Chemistry Beşevler, Ankara TURKEY Tel : / 1545 or 1264 Fax : mkalkan@ankara.edu.tr 1. EDUCATION B. Sc. : Ankara University, Science Faculty, Dept of Chemistry, September June 1999 M. Sc. : Ankara University, Science Faculty, Dept of Chemistry, September Agust 2002 Ph. D. : Ankara University, Science Faculty, Dept of Chemistry, September January 2008 Assoc. Prof. Dr. : March AREAS OF RESEARCH Organometallic synthesis using Group 1, 2, 11 and 12 organometallics, Catalysis, Kinetics and mechanism of organometallic reactions 3. FELLOWSHIPS July September 2001 : Turkish Scientific and Technical Research Council (TUBITAK) Scholarship January September 2007 : Research fellow in Turkish Scientific and Technical Research Council (TUBITAK) Project, Project No. TBAG 106T ACADEMIC CAREER January 2002 January 2008 : Research assistant, Ankara University, Science Faculty, Dept of Chemistry January March 2016 : Dr. Research assistant, Ankara University, Science Faculty, Dept of Chemistry March : Assoc. Prof. Dr. Ankara University, Science Faculty, Dept of Chemistry

2 Assoc. Prof. Dr. MELİKE (KOÇOĞLU) KALKAN S TEACHING ACTIVITY COURSES UNDERGRADUATE : KİM 101 General Chemistry I KİM 113 General Chemistry I CHM 126 Organic Chemistry KİM 134 Organic Chemistry KİM 241 Organic Chemistry I KİM 242 Organic Chemistry II KİM 354 Organic Chemistry Laboratory I KM 377 Organic Chemistry Laboratory KİM 475 Organic Chemistry Laboratory II KİM 499 Space Chemistry Assoc. Prof. Dr. MELİKE (KOÇOĞLU) KALKAN S PUBLICATIONS 1. PAPERS A. International (SCI) papers A1. E. Erdik and M. Koçoğlu, Revisiting the amination of organozincs with benzenediazonium tetrafluoroborate, Main Group Metal chemistry, 2002, 25(10), A2. E. Erdik and M. Koçoğlu, A brief survey on the copper catalyzed allylation of alkylzinc and Grignard reagents under Barbier conditions Appl. Organometal. Chem., 2006, 20, A3. E. Erdik and M. Koçoğlu, Copper catalyzed magnesium-barbier reaction for -selective alkyl-allyl coupling Tetrahedron Lett., 2007, 48(24), A4. E. Erdik and M. Koçoğlu, An insight into copper catalyzed allylation of alkyl zinc halides. Comparison of reactivity profiles for catalytic and stoichiometric alkylzinc copper reagents Journal of Organometallic Chemistry, 2009, 694,

3 A5. E. Erdik, Ö. Ömür Pekel and M. Kalkan, Reactivity of mixed organozinc and organocopper reagents. 3. Atom economic electrophilic amination of methyl arylzinc reagents Appl. Organometal. Chem., 2009, 23, A6. M. Kalkan and E. Erdik, Reactivities of mixed organozinc and mixed organocopper reagents. Part 7. Comparison of the transfer rate of the same group in allylation of mixed and homo diorganozinc reagents J. Phys. Org. Chem. 2013, 26, A7. E. Erdik, F. Eroğlu, M. Kalkan, Ö. Ömür Pekel, D. Özkan, E. Z. Serdar, Reactivities of mixed organozinc and mixed organocopper reagents: 9. Solvent dependence of group transfer selectivity in sp 3 C coupling and acylation of mixed diorganocuprates and diorganozincs Journal of Organometallic Chemistry, 2013, , A8. M. Kalkan Reactivity of mixed organozinc and mixed organocopper reagents: 11. Nickel catalyzed atom-economic aryl-allyl coupling of mixed (n-alkyl)(aryl)zincs Appl. Organometal. Chem., 2014, 28(9), A9. M. Kalkan and E. Erdik Reactivity of Mixed Organozinc and Mixed Organocopper Reagents: 14. Phosphine-nickel catalyzed aryl-allyl coupling of (n-butyl)(aryl)zincs. Ligand and substrate control on the group selectivity and regioselectivity Journal of Organometallic Chemistry, 2016, 818, A10. M. Kalkan, E. Erdik and Ö. Ömür Pekel Revisiting Allylic Coupling of Grignard Reagents. Nano Copper Catalyzed One-Pot α-selective Aryl-Allyl Coupling Organic Preparations and Procedures International, 2017, 49(5), A11. Ö. Ömür Pekel, E. Erdik and M. Kalkan Synthesis of some ketones via nano-nickel oxide catalyzed acylation of arylzinc reagents; strategy involving the use of mixed (methyl)(aryl)zincs Turkish Journal of Chemistry, 2018, 42,

4 B. National Papers B1. M. Koçoğlu Kalkan, Atom ekonomisi ve diğer yeşil reaksiyon ölçümleri Sigma Mühendislik ve Fen Bilimleri Dergisi, 2012, 30(1), B2. M. Kalkan Allylation Of Aryl Grignard Reagents in the Presence of Transition Metal Catalysis and Organic Catalysis Journal of the Turkish Chemical Society A, Chemistry (JOTCSA), 2017, 4(3), ) PRESENTATIONS TO SCIENTIFIC MEETINGS C. International Presentations to Scientific Meetings C1. M. Kalkan and E. Erdik, Reactivities of Mixed Organozinc Reagents and Comparison of the Transfer Rate of the Same Group in Allylation of Mixed and Homo Diorganozinc Reagents 44th IUPAC Word Chemistry Congress and the 47th IUPAC General Assembly, August 2013, İstanbul. Poster Presentations. C2. M. Kalkan Nickel catalyzed atom-economic allylic coupling of mixed arylzincs 8th Asian-European Symposium on Metal-Mediated Efficient Organic Synthesis, September 2014, Çeşme-İzmir. Poster Presentations. C3. M. Kalkan Phosphine-Nickel Catalyzed Aryl-Allyl Coupling of (n-butyl)(aryl)zincs. Ligand and Substrate Control on the Group Selectivity and Regioselectivity 2nd International Turkic World Conference on Chemical Sciences and Technologies (ITWCCST), October 2016, Üsküp-Makedonya. Oral Presentations. D. National Presentations to Scientific Meetings D1. E. Erdik and M. Koçoğlu, Electrophilic amination of organozinc reagents with benzene diazonium tetrafluoroborate, XVII. Turkish Chemical Congress, September 2003, İstanbul. Oral Presentation. D2. E. Erdik and M. Koçoğlu, Alkilçinko Reaktiflerinin Allilik Bileşiklerle Barbier Türü Eşleşmesi, XX. Turkish Chemical Congress, September 2006, Kayseri. Oral Presentation.

5 D3. E. Erdik and M. Koçoğlu, Magnezyum-Barbier Koşullarında Bakır Katalizli Rejioselektif Alkil-Allil Eşleşmesi, XXI. Turkish Chemical Congress, August 2007, Malatya. Oral Presentation. D4. E. Erdik and M. Koçoğlu, Alkilçinko Reaktiflerinin Bakır Katalizli Allilik Eşleşmesi Mekanizması XXII. Turkish Chemical Congress, October 2008, Kıbrıs. Oral Presentation. D5. E. Erdik and M. Koçoğlu Alkilçinko Reaktiflerinin Allilik Eşleşmesinde Rejioselektiflik Kontrolü XXII. Turkish Chemical Congress, October 2008, Kıbrıs. Poster Presentation. D6. E. Erdik, Ö. Ömür Pekel and M. Kalkan, Karışık Diorganoçinko Bileşiklerinin Elektrofilik Aminasyonu. Arilaminlerin Atom Ekonomik Sentezi XXIII. Turkish Chemical Congress, June 2009, Sivas. Oral Presentation. D7. M. Kalkan and E. Erdik, Karışık ve Homo Diorganoçinko Reaktiflerinin Allillenme Reaksiyonunda Aynı Grubun İletim Hızının Kıyaslanması I. National Organic Chemistry Congress, October 2013, Sakarya. Oral Presentation.. D8. M. Kalkan Karışık Diorganoçinko Reaktiflerinin Nikel Katalizli Allilik Eşleşmesi II. National Organic Chemistry Congress, September 2014, Ankara. Oral Presentation.. D9. M. Kalkan Ligand Controlled Nickel Catalyzed Allyl Coupling Of Mixed Arylzinc Reagents, 28. Ulusal Kimya Kongresi, August 2016, Mersin. Oral Presentation. D10. M. Kalkan, E. Erdik, Ö. Ömür Pekel Aril Grignard Reaktiflerinin Nano CuO Katalizli Tek Basamaklı α-seçici Allilik Eşleşmesi VI. National Anorganic Chemistry Congress, May 2017, Burdur. Oral Presentation. D11. M. Kalkan Fenilmagnezyum Bromür ün Krotil Klorür ile Allilik Eşleşme Reaksiyonunda Geçiş Metali Katalizi ve Organokataliz Etkisi VI. National Anorganic Chemistry Congress, May 2017, Burdur. Poster Presentation.

6 3) RESEARCH PROJECTS Turkish Scientific and Technical Research Council (TUBITAK) Projects 1. E. Erdik, F. Eroğlu, T. Daşkapan, M. Koçoğlu ve D. Kahya, New methods for amination of main group organometallic compounds,turkish Scientific and Technical Research Council ( TÜBİTAK) Project, Project No.TBAG-1983 (100T087), February February Araştırmacı. 2. E. Erdik, M. Koçoğlu, Ö. Ömür Pekel, D. Kayagil E. Z. Serdar Synthetic and mechanistic investigation of group selectivity in C-C coupling of mixed diorganozinc and copper reagents Turkish Scientific and Technical Research Council ( TÜBİTAK) Project, Project No. TBAG- 106T 644, January January Araştırmacı. 3. M. Kalkan, E.Erdik Allylic coupling of mixed diorganozinc reagents. Group selectivity and its control. Developing new synthetic methods for aryl-allyl coupling using mixed diorganozinc reagents Turkish Scientific and Technical Research Council (TÜBİTAK) 112T886, Yürütücü. 4. Ankara Üniversitesi nde Nitelikli Araştırma Projesi Üretim Altyapısının Geliştirilmesi TÜBİTAK 114K506, Araştırmacı. Scientific Research Projects (BAP) 1. E. Erdik, F. Eroğlu, M. Koçoğlu, Ö. Ömür ve S. Ateş New methods for organometallic synthesis of tertiary amines. Kinetics and mechanism of elektrophilic amination, Ankara University Research Fund (BAP) Project, Project No.BAP No.lu Proje, October October Araştırmacı. 2. E. Erdik, M. Koçoğlu ve S. Ateş Amination of Grignard reagents with N,N-disübstituted O-sülfonylhydroxylamines. Kinetics and mechanism of carbanion amination Ankara University Research Fund (BAP) Project, Project No.BAP HPD , Araştırmacı.

7 3. E. Erdik, M. Koçoğlu, Ö. Ömür Pekel The use of mixed diorganozinc and copper reagents in allylation and acylation reactions. Synthetic and mechanistic investigation Ankara University Research Fund (BAP) Project, Project No. BAP 09B , Araştırmacı. 4. E. Erdik, M. Kalkan Atom economic allylation reactions of mixed diorganozinc reagents Ankara University Research Fund (BAP) Project, Project No. BAP 12H , Araştırmacı. 4. M. SC AND PH. D. THESES 1. "New methods for amination of organolithium Grignard, organocopper and organozinc reagens", M. Koçoğlu, M. Sc. Thesis, Ankara University, Synthetic investigation of allylation of organomagnesium and zinc reagents and mechanistic investigation of allylation of alkylzinc reagents, M. Koçoğlu, Ph. D. Thesis, Ankara University, 2008.

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